Product ID:CPE133466, PROCHLOR CONCENTRATED POOL (SUP DAT)
MSDS Date:03/03/1989
FSC:6850
NIIN:00N078465
MSDS Number: CGGHL

OLIN CORP

120 LONG RIDGE RD
STAMFORD, CT 06904-1355
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: 8X135

OLIN CORP CHEMICALS GROUP

STAMFORD, CT 06904 US

Telephone: 203-356-3449,CHEMTREC 800-242-9300

Cage: 53084

S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3,5-TRICHLORO-;

CAS: 87-90-1

RTECS: XZ1925000

Fraction By Weight: 96-100%

OSHA PEL N/K

ACGIH TLV: N/K

S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3-DICHLORO-;

CAS: 2782-57-2

RTECS: XZ1845000

Fraction By Weight: 0-4%

OSHA PEL N/K

ACGIH TLV: N/K

GI TRACT, INCL STOM & INTESTINES, W/NAUS,

RTECS: 9999999ZZ

MAY CAUSE IMPAIRMENT OF LUNG FUNC &

RTECS: 9999999ZZ

FROM SINGLE EXPOS EXCEPT FOR EFTS SECONDARY TO TISS

RTECS: 9999999ZZ

IF PERS EXPERIENCES NAUS, HDCH/DIZZ,

RTECS: 9999999ZZ

UNTIL SYMPS DISAPPEAR. IF BRTHG IS DFCLT, ADMIN

RTECS: 9999999ZZ

ENOUGH VAP TO LOSE CONSCIOUSNESS, MOVE TO FRESH AIR

RTECS: 9999999ZZ

SHOULD BE GIVEN IMMED. IN ALL CASES, ENSURE ADEQ

RTECS: 9999999ZZ

THIS MATL. USER OF THIS MATL HAS

RTECS: 9999999ZZ

ALL RELEVANT LOC, STATE & FED LAWS & REGS REGARDING

RTECS: 9999999ZZ

MAY BE SUPPRESSED BY USE OF WATER FOG. WATER

RTECS: 9999999ZZ

MATL INTO WATER SOURCE AS SOON AS POSS. BEGIN

RTECS: 9999999ZZ

NOT CONTAM SPILL MATL W/ANY ORG MATLS, AMMONIA,

RTECS: 9999999ZZ

DRY DEDICATED EQUIP & PLACE IN CLEAN DRY CONTR.

RTECS: 9999999ZZ

MATL MAY BE NEUT FOR DISP; YOU ARE REQUESTED TO

RTECS: 9999999ZZ

OPERATION. ADDNL NIOSH APPRVD RESP PROT IS NEC WHEN

RTECS: 9999999ZZ

TO USE HALF MASK CARTRIDGE TYPE, W/CHLORINE

RTECS: 9999999ZZ

NIOSH APPRVD SCBA. ADDNL PROT CLTHG MUST BE WORN TO

RTECS: 9999999ZZ

TO BOOTS, GLOVES, HARD HAT, SPLASH-PROOF GOGG, &

RTECS: 9999999ZZ

MATLS FOR RESPONSE TO THIS MATL ARE NEOPRENE,

RTECS: 9999999ZZ

IF THIS

RTECS: 9999999ZZ

NITROGEN TRICHLORIDE GAS MAY OCCUR AND AN EXPLOSIVE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL RAT): 490 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED/INGESTED, IF
EXPOSED TO SKIN/EYES. ACUTE: INHAL: IRRIT TO NOSE, MOUTH, THROAT &
LUNGS. MAY CAUSE BURNS TO RESP TRACT W/PRODUCTION OF LUNG EDEMA
WHICH CAN RSLT IN SHORTNESS OF BRTH, WHEEZING, CHOKING, CHEST PAIN
& IMPAIRMENT OF LUNG FUNC. INHAL OF HIGH CONCS CAN RSLT IN PERM
LUNG (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DMG. EYE: SEV IRRIT &/BURNS CAN
OCCUR. MAY CAUSE IMPAIRMENT OF VISION & CORNEAL DMG. SKIN: DERMAL
EXPOS CAN CAUSE SEV IRRIT &/BURNS W/REDNESS, SWELL & SCAB FORM.
PRLNG SKIN EXPOS MAY CAUSE D ESTRUCTION OF DERMIS W/IMPAIRMENT OF
SKIN AT SITE OF CONT TO REGENERATE. INGEST: IRRIT &/BURNS CAN OCCUR
TO (ING 3)
Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY AND
CARDIOVASCULAR DISEASE.

First Aid:EYES: IMMED FLUSH W/LGE AMTS OF WATER FOR AT LEAST 15 MIN,
OCCAS LIFTING UPPER & LOWER EYELIDS. CALL MD IMMED. SKIN: IMMED
FLUSH W/WATER FOR AT LEAST 15 MIN. CALL MD. IF CLTHG COMES IN CONT
W/PROD, IT SHOULD BE REMOVED IMMED & LAUNDERED BEFORE REUSE.
INGEST: IMMED DRINK LGE QTYS OF WATER. DO NOT INDUCE VOMIT. CALL MD
IMMED. DO NOT GIVE ANYTHING BY MOUTH IF PERS IS UNCON/HAVING
CONVLS. (ING 6)

Extinguishing Media:ON SMALL FIRES, USE WATER SPRAY OR FOG. ON LARGE
FIRES, USE HEAVY DELUGE OR FOG STREAMS.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . USE
WATER TO COOL CONTRS EXPOSED TO FIRE. FLOODING AMTS OF WATER MAY BE
REQUIRED BEFORE EXTING CAN BE (SUP DAT)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:HAZ CONCS IN AIR MAY BE FOUND IN LOC SPILL
AREA & IMMED DOWNWIND. IF SPILL IS STILL DRY, DO NOT PUT WATER
DIRECTLY ON THIS PROD AS GAS EVOLUTION MAY OCCUR. IF MATL IS WET,
CONT OCEAN NETWORK FOR PROPE R STABILIZATION PROC. AIR RELEASE:
VAPS(ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT TAKE INTERNALLY. AVOID CONTACT
WITH SKIN, EYES AND CLOTHING.
Other Precautions:STORE IN A CLEAN DRY WELL-VENTILATED AREA. KEEP AWAY
FROM INCOMPATIBLE CHEMICALS. DO NOT STORE AT TEMPERATURES ABOVE 60C
(140F).

Respiratory Protection:WEAR NIOSH APPRVD RESP EQUIPPED W/CHEM CARTRIDGE
FOR PROT AGAINS CHLORINE GAS & DUST/MIST TYPE PREFILTER. HALF-MASK
WORN W/CHEM SFTY GOGG/FULL FACE RESP WORN W/OUT.
Ventilation:USE LOCAL EXHAUST VENTILATION TO MINIMIZE DUST LEVELS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . NEOPRENE APRON, BOOTS AND PROTECTIVE SUIT.
Work Hygienic Practices:UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH
WATER.
Supplemental Safety and Health
TRADE NAME/PART #: CHLORINATING STICKS. PH (1% SOLN): 2.7-2.9. FIRE
FIGHT PROC: ACCOMPLISHED. DO NOT USE DRY CHEM EXTING CONTAINING
AMMONIA CMPDS. CNDTNS TO AVOID: SLIGHTLY WET PROD (WILL EVOLVE
NITRO GEN TRICHLORIDE). MATLS TO AVOID: DRY FIRE EXTING CONTAINING
AMMONIUM CMPDS.

Spec Gravity:>1.0
pH:SUPDAT
Solubility in Water:1.2% @ 25C
Appearance and Odor:WHITE GRANULAR SOLID/TABLET-FORM PROD; SHARP,
CHLORINE-LIKE, BLEACH ODOR

Stability Indicator/Materials to Avoid:YES
ORG MATLS, OILS, GREASE, SAWDUST, REDUCING AGENTS, NITROGEN-CONTAINING
CMPDS, OTHER OXIDIZERS, ACIDS, BASES, (SUP DAT)
Stability Condition to Avoid:TEMPS > 225C (437F). CONT W/SML AMTS OF
WATER MAY RSLT IN EXOTHERMIC RXN W/LIBERATION OF TOX FUMES. DAMP OR
(SUP DAT)
Hazardous Decomposition Products:NITROGEN TRICHLORIDE, CHLORINE,
NITROUS OXIDES, CYANATES, CARBON MONOXIDE, CARBON DIOXIDE.

Waste Disposal Methods:EPA HAZ WASTE NUMBER IF PROD BECOMES WASTE:
D001. AS HAZ SOLID WASTE, IT MUST BE DISP OF I/A/W LOC, STATE & FED
REGS IN PERMITTED HAZ WASTE TREATMENT, STOR & DISP FACILITY BY
TREATMENT. CARE MUST BE T AKEN TO PVNT ENVIRON CONTAM FROM USE
OF(ING 10)

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disclaims all liability for its use. Any person utilizing this
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particular situation.